Ozone (O3) is the triatomic, allotropic form of oxygen (O2). It is an unstable gas with a pungent odor. Since ozone is unstable, it must be generated at the point of application.
The Ozone molecule, having a molecular weight of 48, is made up of three oxygen atoms bound by equal oxygen-oxygen bonds at an obtuse angle of 116o49’. This structure is inherently unstable and is the reason for ozone’s powerful oxidizing ability. Ozone has approximately 150% the oxidizing potential of chlorine. The physical properties of ozone and comparative oxidizing potentials for other chemical oxidants are presented in Table 1 and Table 2, respectively.
Table 1Physical Constants of Ozone | Table 2Comparative Oxidizing Potentials,25oC Volts | |||
Molecular weight, g/g-mol | 48.0 | Fluorine (F2) | 2.87 | |
Boiling point, oC | -111.9 | Ozone (O3) | 2.07 | |
Melting point, oC | -193 | Hydrogen Peroxide (H2O2) | 1.78 | |
Gas density, 0oC grams/liter | 2.144 | Potassium Permanganate (KMnO4) | 1.70 | |
Critical temperature, oC | -12.1 | Hyprobromous Acid (HOBr) | 1.59 | |
Critical pressure, atm. | 54.6 | Hypochlorous Acid (HOCl) | 1.49 | |
Critical volume, cc/mol | 147.1 | Chlorine (Cl2) | 1.36 | |
Chlorine dioxide (ClO2) | 1.27 | |||
Oxygen (O2) | 1.23 | |||
Chromic Acid (H2CrO4) | 1.21 | |||
Bromine (Br2) | 1.09 | |||
Nitric Acid (HNO3) | 0.94 | |||
Iodine (I2) | 0.54 |